As confirmed by Fabrizio Romano, RB Leipzig and Hoffenheim have reached an agreement over the transfer of Angeliño.
The transfer will be a long loan deal until June 2023, with Hoffenheim having the option to buy the Galician full-back at the end of the season.
The two sides have settled on a fee of €20 million if Hoffenheim wishes to sign the 25-year-old permanently.
In the past, Angeliño was linked with Barcelona, however, the Blaugrana never submitted a formal offer to sign him.
The A Coruña native came through the Deportivo La Coruña youth system before transferring to the Manchester City youth academy.
After a couple of loan spells in Spain and the Netherlands, he finally made his debut in the Premier League in 2019.
Angeliño never quite managed to break into the Manchester City starting XI. He moved on loan to RB Leipzig in January 2020 before the German side making his transfer permanent a year later.