Boulaye Dia opened the scoring for Villarreal against Liverpool after just three minutes at a packed Estadio La Cerámica on Tuesday night.
The goalscorer got the nod in attack after Arnaut Danjuma missed out through injury.
It’s Dia’s first Champions League goal for Unai Emery’s side. He has only played 176 minutes in total in the competition before tonight.
The early opener took the game to 1-2 on aggregate, giving Liverpool the advantage of reaching this year’s final.